Wednesday, February 15, 2017

How Does Orange Peel Pop a Balloon?

Isn’t that cool?  The juice from an orange peel causes a balloon to pop.  When I first saw this effect I immediately thought to myself, “what is the chemistry involved in this experiment?” After quickly searching the web, I found several claims that a compound in orange peels called limonene (Figure 1) is responsible for this effect.  Limonene is a hydrocarbon, which means that molecules of limonene are composed of only carbon and hydrogen atoms.  Limonene is responsible for the wonderful smell of oranges, and it is a liquid at room temperature.

Figure 1:  Chemical structure of limonene
Because limonene is a hydrocarbon and hydrocarbons are non-polar molecule, one would expect limonene to be non-polar.

So what does all this chemical information have to do with balloons popping when squirted with orange peel juice?  Well, balloons are made primarily of rubber.  Like limonene, rubber is a hydrocarbon, so it’s non-polar as well.  It is well known by chemists that non-polar substances dissolve well in other non-polar substances (we like to say that “like dissolves like”).  Therefore, when the limonene oil contacts the surface of a balloon, some of the rubber balloon dissolves in the limonene.  This weakens the balloon, causing it to pop. 

Chemical structure of rubber (chemical name: cis-poly isoprene).  The pattern of atoms seen here is repeated hundreds of times over to make a very long molecule called a polymer.   

We wanted to test this claim that limonene oil is responsible for balloons popping.  So we extracted some limonene oil from orange peels using a procedure published in the Journal of Chemical Education (link is external).  Sure enough, limonene placed onto a balloon causes it to pop:

Interestingly, we have observed that not all balloons pop when squirted with an orange peel:

Why is it that some balloons pop in this experiment, while others do not?  It has to do with chemistry, of course!  The cis-poly isoprene molecules in rubber are very long molecules called polymers.  In natural rubber, these long molecular strands can readily separate from one another.  Because of this molecular property, it is easy to get rubber to break into pieces or to dissolve in various solvents.  This property of rubber can be changed through a process called vulcanization.  During vulcanization, rubber is treated with sulfur.  Vulcanization causes polymer strands to become connected by sulfur atoms in what is called a cross-link.  While the chemistry involved is more complex than indicated in the figure, the effect of vulcanization on rubber makes it very difficult for polymer molecules to separate from one another.  Because of this, vulcanized rubber is tougher to break apart and more difficult to dissolve than normal rubber.   

Simplified structure of cross-linked rubber.  The red arrow identifies a cross-link between two polymer strands.

Now that you know a bit about the chemistry of balloons, I think you might be able guess which balloons pop when squirted with the juice from an orange peel, and which balloons do not.  Most balloons are made of vulcanized rubber1, presumably to keep them from breaking easily when stretched.  When a balloon made of vulcanized rubber is squirted with limonene or an orange peel, it doesn’t break.  Water balloons are not made of vulcanized rubber1, because people generally want these balloons to be somewhat breakable.  Because of this difference in its chemistry, a water balloon pops when squirted with limonene or orange peel juice!

We are interested to learn what types of easy-to-find, non-polar liquids can be used to cause balloons to pop.  Curiously, we have tested acetone and found that it does not cause the balloons to pop.  If you find some fluids that cause balloons to pop, please let us know.  Also, if anyone has comments on our interpretation of the chemistry presented herein, we welcome your insights! 

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Presented By:
Sunburst Oranges
180 South “E” Street
Porterville, CA  93257

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